Vibrational relaxation of NO+(υ) by O2(1Δg) molecules

I. Dotan; S. E. Barlow; E. E. Ferguson

doi:10.1016/0009-2614(85)87150-5

Vibrational relaxation of NO⁺(υ) by O₂(¹Δ_g) molecules

I. Dotan
, S. E. Barlow
, E. E. Ferguson

פרסום מחקרי: פרסום בכתב עת › מאמר › ביקורת עמיתים

תקציר

The rate constant for NO⁺(υ) vibrational relaxation by metastable O₂(¹Δ_g) molecules is found to be (3±2)×10^-10 cm³ s^-1 at room temperature, in contrast to the lack of vibrational quenching of NO⁺(υ) by ground-state O₂(³Σ) molecules, for which the quenching rate constant <10^-12 cm³ s^-1. This suggests that NO⁺(¹Σ)+O₂(¹Δ) follows a much more attractive potential curve than NO⁺(¹Σ)+O₂(³Σ).

שפה מקורית	אנגלית
עמודים (מ-עד)	38-40
מספר עמודים	3
כתב עת	Chemical Physics Letters
כרך	121
מספר גיליון	1-2
מזהי עצם דיגיטלי (DOIs)	https://doi.org/10.1016/0009-2614(85)87150-5
סטטוס פרסום	פורסם - 1 נוב׳ 1985
פורסם באופן חיצוני	כן

גישה למסמך

10.1016/0009-2614(85)87150-5

קבצים וקישורים אחרים

Link to publication in Scopus

פורמט ציטוט ביבליוגרפי

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title = "Vibrational relaxation of NO+(υ) by O2(1Δg) molecules",

abstract = "The rate constant for NO+(υ) vibrational relaxation by metastable O2(1Δg) molecules is found to be (3±2)×10-10 cm3 s-1 at room temperature, in contrast to the lack of vibrational quenching of NO+(υ) by ground-state O2(3Σ) molecules, for which the quenching rate constant <10-12 cm3 s-1. This suggests that NO+(1Σ)+O2(1Δ) follows a much more attractive potential curve than NO+(1Σ)+O2(3Σ).",

author = "I. Dotan and Barlow, \{S. E.\} and Ferguson, \{E. E.\}",

year = "1985",

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doi = "10.1016/0009-2614(85)87150-5",

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AU - Dotan, I.

AU - Barlow, S. E.

AU - Ferguson, E. E.

PY - 1985/11/1

Y1 - 1985/11/1

N2 - The rate constant for NO+(υ) vibrational relaxation by metastable O2(1Δg) molecules is found to be (3±2)×10-10 cm3 s-1 at room temperature, in contrast to the lack of vibrational quenching of NO+(υ) by ground-state O2(3Σ) molecules, for which the quenching rate constant <10-12 cm3 s-1. This suggests that NO+(1Σ)+O2(1Δ) follows a much more attractive potential curve than NO+(1Σ)+O2(3Σ).

AB - The rate constant for NO+(υ) vibrational relaxation by metastable O2(1Δg) molecules is found to be (3±2)×10-10 cm3 s-1 at room temperature, in contrast to the lack of vibrational quenching of NO+(υ) by ground-state O2(3Σ) molecules, for which the quenching rate constant <10-12 cm3 s-1. This suggests that NO+(1Σ)+O2(1Δ) follows a much more attractive potential curve than NO+(1Σ)+O2(3Σ).

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JO - Chemical Physics Letters

JF - Chemical Physics Letters

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