The effect of alkali-chloride on the thermal hydrolysis of hydrated magnesium-chloride

Shlomo Shoval; S. Yariv

doi:10.1016/0040-6031(85)86003-2

The effect of alkali-chloride on the thermal hydrolysis of hydrated magnesium-chloride

Shlomo Shoval, S. Yariv

Earth Sciences discipline

Research output: Contribution to journal › Article › peer-review

Abstract

DTA, TG and DTG curves were recorded for mixtures of hydrated MgCl₂ with NaCl, KC1 and CsCl. Infrared spectra of the mixtures were recorded after they had been heated to several temperatures. CsCl forms a stable solid solution with MgCl₂ and the thermal hydrolysis of the salt is prevented. The solid solution formed with KC1 is less stable than that formed with CsCl and hydrated Mg is thermally hydrolyzed to a small extent. No solid solution is formed with NaCl and MgCl₂ is thermally hydrolyzed in the presence of this salt.

Original language	English
Pages (from-to)	819-822
Number of pages	4
Journal	Thermochimica Acta
Volume	92
Issue number	C
DOIs	https://doi.org/10.1016/0040-6031(85)86003-2
State	Published - 15 Sep 1985

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10.1016/0040-6031(85)86003-2

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abstract = "DTA, TG and DTG curves were recorded for mixtures of hydrated MgCl2 with NaCl, KC1 and CsCl. Infrared spectra of the mixtures were recorded after they had been heated to several temperatures. CsCl forms a stable solid solution with MgCl2 and the thermal hydrolysis of the salt is prevented. The solid solution formed with KC1 is less stable than that formed with CsCl and hydrated Mg is thermally hydrolyzed to a small extent. No solid solution is formed with NaCl and MgCl2 is thermally hydrolyzed in the presence of this salt.",

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AU - Yariv, S.

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N2 - DTA, TG and DTG curves were recorded for mixtures of hydrated MgCl2 with NaCl, KC1 and CsCl. Infrared spectra of the mixtures were recorded after they had been heated to several temperatures. CsCl forms a stable solid solution with MgCl2 and the thermal hydrolysis of the salt is prevented. The solid solution formed with KC1 is less stable than that formed with CsCl and hydrated Mg is thermally hydrolyzed to a small extent. No solid solution is formed with NaCl and MgCl2 is thermally hydrolyzed in the presence of this salt.

AB - DTA, TG and DTG curves were recorded for mixtures of hydrated MgCl2 with NaCl, KC1 and CsCl. Infrared spectra of the mixtures were recorded after they had been heated to several temperatures. CsCl forms a stable solid solution with MgCl2 and the thermal hydrolysis of the salt is prevented. The solid solution formed with KC1 is less stable than that formed with CsCl and hydrated Mg is thermally hydrolyzed to a small extent. No solid solution is formed with NaCl and MgCl2 is thermally hydrolyzed in the presence of this salt.

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The effect of alkali-chloride on the thermal hydrolysis of hydrated magnesium-chloride

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