Steric Hindrance of NH3Diffusion on Pt(111) by Co-Adsorbed O-Atoms

Dmitriy Borodin, Oihana Galparsoro, Igor Rahinov, Jan Fingerhut, Michael Schwarzer, Stefan Hörandl, Daniel J. Auerbach, Alexander Kandratsenka, Dirk Schwarzer, Theofanis N. Kitsopoulos, Alec M. Wodtke

Research output: Contribution to journalArticlepeer-review


A detailed velocity-resolved kinetics study of NH3thermal desorption rates from p(2 × 2) O/Pt(111) is presented. We find a large reduction in the NH3desorption rate due to adsorption of O-atoms on Pt(111). A physical model describing the interactions between adsorbed NH3and O-atoms explains these observations. By fitting the model to the derived desorption rate constants, we find an NH3stabilization on p(2 × 2) O/Pt(111) of 0.147-0.014+0.023eV compared to Pt(111) and a rotational barrier of 0.084-0.022+0.049eV, which is not present on Pt(111). The model also quantitatively predicts the steric hindrance of NH3diffusion on Pt(111) due to co-adsorbed O-atoms. The derived diffusion barrier of NH3on p(2 × 2) O/Pt(111) is 1.10-0.13+0.22eV, which is 0.39-0.14+0.22eV higher than that on pristine Pt(111). We find that Perdew Burke Ernzerhof (PBE) and revised Perdew Burke Ernzerhof (RPBE) exchange-correlation functionals are unable to reproduce the experimentally observed NH3-O adsorbate-adsorbate interactions and NH3binding energies at Pt(111) and p(2 × 2) O/Pt(111), which indicates the importance of dispersion interactions for both systems.

Original languageEnglish
Pages (from-to)21791-21799
Number of pages9
JournalJournal of the American Chemical Society
Issue number47
StatePublished - 30 Nov 2022

Bibliographical note

Publisher Copyright:
© 2022 American Chemical Society. All rights reserved.


  • Adsorption
  • Diffusion
  • Kinetics


Dive into the research topics of 'Steric Hindrance of NH3Diffusion on Pt(111) by Co-Adsorbed O-Atoms'. Together they form a unique fingerprint.

Cite this