Rate constants for the reactions of O-, O2 -, NO2-, CO3-, and CO4- with HCl and ClO- with NO, NO2, SO2, and CO2 at 300 K

I. Dotan; D. L. Albritton; F. C. Fehsenfeld; G. E. Streit; E. E. Ferguson

doi:10.1063/1.435717

Rate constants for the reactions of O^-, O₂ ^-, NO₂^-, CO₃^-, and CO₄^- with HCl and ClO_- with NO, NO₂, SO₂, and CO₂ at 300 K

I. Dotan, D. L. Albritton, F. C. Fehsenfeld, G. E. Streit, E. E. Ferguson

Research output: Contribution to journal › Article › peer-review

Abstract

The rate constants for several ion-molecule reactions involving chlorine-containing ions or molecules have been measured at 300 K with a flowing afterglow apparatus. These include the reaction of O^- with CCl ₄, several negative ions with HCl, ClO^- with several neutrals, and Cl^- with O₃. These reactions are used to place limits on the electron affinity of ClO: E.A.(ClO)=1.95±0.25 eV. The implications of these results to the negative ion chemistry of the atmosphere are discussed.

Original language	English
Pages (from-to)	5414-5416
Number of pages	3
Journal	Journal of Chemical Physics
Volume	68
Issue number	12
DOIs	https://doi.org/10.1063/1.435717
State	Published - 1977
Externally published	Yes

Access to Document

10.1063/1.435717

Cite this

@article{cf9181124f694b228f42b26a935c8342,

title = "Rate constants for the reactions of O-, O2 -, NO2-, CO3-, and CO4- with HCl and ClO- with NO, NO2, SO2, and CO2 at 300 K",

abstract = "The rate constants for several ion-molecule reactions involving chlorine-containing ions or molecules have been measured at 300 K with a flowing afterglow apparatus. These include the reaction of O- with CCl 4, several negative ions with HCl, ClO- with several neutrals, and Cl- with O3. These reactions are used to place limits on the electron affinity of ClO: E.A.(ClO)=1.95±0.25 eV. The implications of these results to the negative ion chemistry of the atmosphere are discussed.",

author = "I. Dotan and Albritton, {D. L.} and Fehsenfeld, {F. C.} and Streit, {G. E.} and Ferguson, {E. E.}",

year = "1977",

doi = "10.1063/1.435717",

language = "אנגלית",

volume = "68",

pages = "5414--5416",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "12",

}

TY - JOUR

T1 - Rate constants for the reactions of O-, O2 -, NO2-, CO3-, and CO4- with HCl and ClO- with NO, NO2, SO2, and CO2 at 300 K

AU - Dotan, I.

AU - Albritton, D. L.

AU - Fehsenfeld, F. C.

AU - Streit, G. E.

AU - Ferguson, E. E.

PY - 1977

Y1 - 1977

N2 - The rate constants for several ion-molecule reactions involving chlorine-containing ions or molecules have been measured at 300 K with a flowing afterglow apparatus. These include the reaction of O- with CCl 4, several negative ions with HCl, ClO- with several neutrals, and Cl- with O3. These reactions are used to place limits on the electron affinity of ClO: E.A.(ClO)=1.95±0.25 eV. The implications of these results to the negative ion chemistry of the atmosphere are discussed.

AB - The rate constants for several ion-molecule reactions involving chlorine-containing ions or molecules have been measured at 300 K with a flowing afterglow apparatus. These include the reaction of O- with CCl 4, several negative ions with HCl, ClO- with several neutrals, and Cl- with O3. These reactions are used to place limits on the electron affinity of ClO: E.A.(ClO)=1.95±0.25 eV. The implications of these results to the negative ion chemistry of the atmosphere are discussed.

UR - http://www.scopus.com/inward/record.url?scp=36749120057&partnerID=8YFLogxK

U2 - 10.1063/1.435717

DO - 10.1063/1.435717

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:36749120057

SN - 0021-9606

VL - 68

SP - 5414

EP - 5416

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 12

ER -

Rate constants for the reactions of O^-, O₂ ^-, NO₂^-, CO₃^-, and CO₄^- with HCl and ClO_- with NO, NO₂, SO₂, and CO₂ at 300 K

Abstract

Access to Document

Other files and links

Fingerprint

Cite this