Rate constants for the reactions of O2+, NO 2+, NO+, H3O+, CO 3-, NO2-, and halide ions with N2O5 at 300 K

J. A. Davidson; A. A. Viggiano; Carleton J. Howard; I. Dotan; F. C. Fehsenfeld; D. L. Albritton; E. E. Ferguson

doi:10.1063/1.436032

Rate constants for the reactions of O₂⁺, NO ₂⁺, NO⁺, H₃O⁺, CO ₃^-, NO₂^-, and halide ions with N₂O₅ at 300 K

J. A. Davidson, A. A. Viggiano, Carleton J. Howard, I. Dotan, F. C. Fehsenfeld, D. L. Albritton, E. E. Ferguson

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Abstract

The reactions of N₂O₅ with CO₃ ^-, NO₂^-, and the halide ions, F^-, Cl^-, Br^-, and I^-, have been found to be very fast (k∼10^-9 cm³ s^-1) at 300 K and to produce the NO₃^- ion. It is inferred from the thermochemistry of the halide reactions that the neutral products must be XNO₂. The positive ions O₂⁺ and NO₊ react with N₂O₅ to produce NO₂⁺, while H₃O⁺ reacts with N₂O₅ to form NO₂⁺ and H₂NO₃⁺. NO ₂⁺ was observed not to react readily with N ₂O₅.

Original language	English
Pages (from-to)	2085-2087
Number of pages	3
Journal	Journal of Chemical Physics
Volume	68
Issue number	5
DOIs	https://doi.org/10.1063/1.436032
State	Published - 1978
Externally published	Yes

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title = "Rate constants for the reactions of O2+, NO 2+, NO+, H3O+, CO 3-, NO2-, and halide ions with N2O5 at 300 K",

abstract = "The reactions of N2O5 with CO3 -, NO2-, and the halide ions, F-, Cl-, Br-, and I-, have been found to be very fast (k∼10-9 cm3 s-1) at 300 K and to produce the NO3- ion. It is inferred from the thermochemistry of the halide reactions that the neutral products must be XNO2. The positive ions O2+ and NO+ react with N2O5 to produce NO2+, while H3O+ reacts with N2O5 to form NO2+ and H2NO3+. NO 2+ was observed not to react readily with N 2O5.",

author = "Davidson, {J. A.} and Viggiano, {A. A.} and Howard, {Carleton J.} and I. Dotan and Fehsenfeld, {F. C.} and Albritton, {D. L.} and Ferguson, {E. E.}",

year = "1978",

doi = "10.1063/1.436032",

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volume = "68",

pages = "2085--2087",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

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TY - JOUR

T1 - Rate constants for the reactions of O2+, NO 2+, NO+, H3O+, CO 3-, NO2-, and halide ions with N2O5 at 300 K

AU - Davidson, J. A.

AU - Viggiano, A. A.

AU - Howard, Carleton J.

AU - Dotan, I.

AU - Fehsenfeld, F. C.

AU - Albritton, D. L.

AU - Ferguson, E. E.

PY - 1978

Y1 - 1978

N2 - The reactions of N2O5 with CO3 -, NO2-, and the halide ions, F-, Cl-, Br-, and I-, have been found to be very fast (k∼10-9 cm3 s-1) at 300 K and to produce the NO3- ion. It is inferred from the thermochemistry of the halide reactions that the neutral products must be XNO2. The positive ions O2+ and NO+ react with N2O5 to produce NO2+, while H3O+ reacts with N2O5 to form NO2+ and H2NO3+. NO 2+ was observed not to react readily with N 2O5.

AB - The reactions of N2O5 with CO3 -, NO2-, and the halide ions, F-, Cl-, Br-, and I-, have been found to be very fast (k∼10-9 cm3 s-1) at 300 K and to produce the NO3- ion. It is inferred from the thermochemistry of the halide reactions that the neutral products must be XNO2. The positive ions O2+ and NO+ react with N2O5 to produce NO2+, while H3O+ reacts with N2O5 to form NO2+ and H2NO3+. NO 2+ was observed not to react readily with N 2O5.

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Rate constants for the reactions of O₂⁺, NO ₂⁺, NO⁺, H₃O⁺, CO ₃^-, NO₂^-, and halide ions with N₂O₅ at 300 K

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