Quantifying the breakdown of the Born-Oppenheimer approximation in surface chemistry

Keyphrases

• Surface Chemistry 100%
• Born-Oppenheimer Approximation 100%
• Non-adiabatic 80%
• Incidence Energy 20%
• Molecular Beam 20%
• Au(111) 20%
• Adiabatic Potential Energy Surfaces 20%
• Metal Surface 20%
• State-to-state 20%
• Vibrational Excitation 20%
• Surface Temperature 20%
• Nonadiabatic Coupling 20%
• Surface Scattering 20%
• Inelasticity 20%
• Coupling Strength 20%
• Arrhenius 20%
• Relative Magnitude 20%
• Rate-based Model 20%
• Chemical System 20%
• Pre-exponential Factor 20%
• Nonadiabatic Effect 20%
• Scattering Experiments 20%
• Temperature Effect 20%
• Thermal Limits 20%
• Simple Rules 20%
• Chemical Problems 20%

Chemistry

• Surface Chemistry 100%
• Born-Oppenheimer Approximation 100%
• Potential Energy Surface 20%
• Molecular Beam 20%
• Adiabatic Potential 20%
• Vibrational Excitation 20%
• Surface Scattering 20%