Formation of carnallite type double salts by grinding mixtures of magnesium and alkali halides with the same anions

S. Shoval; S. Yariv

doi:10.1007/BF02719027

Formation of carnallite type double salts by grinding mixtures of magnesium and alkali halides with the same anions

S. Shoval, S. Yariv

Earth Sciences discipline

Research output: Contribution to journal › Article › peer-review

Abstract

The formation of carnallite type double salts by grinding mixtures of hydrated magnesium halide and alkali halides with the same anions was investigated by X-ray diffraction, infrared spectroscopy and thermal analysis. Carnallite (KMgCl₃·6H₂O), cesium-carnallite (CsMgCl₃·6H₂O), bromo-carnallite (KMgBr₃·6H₂O) and cesium-bromo-carnallite (CsMgBr₃·6H₂O) were formed by grinding mixtures of MgCl₂·6H₂O with KCl or CsCl and MgBr₂·6H₂O with KBr or CsBr, respectively. Hydrated solid solutions of magnesium in potassium or cesium halides were obtained from that portion of potassium and cesium halides which did not take part in the formation of the double salt.

Original language	English
Pages (from-to)	251-263
Number of pages	13
Journal	Journal of Thermal Analysis and Calorimetry
Volume	51
Issue number	1
DOIs	https://doi.org/10.1007/BF02719027
State	Published - 1998

Access to Document

10.1007/BF02719027

Cite this

@article{37f466891126457f90802c368994c1dd,

title = "Formation of carnallite type double salts by grinding mixtures of magnesium and alkali halides with the same anions",

abstract = "The formation of carnallite type double salts by grinding mixtures of hydrated magnesium halide and alkali halides with the same anions was investigated by X-ray diffraction, infrared spectroscopy and thermal analysis. Carnallite (KMgCl3·6H2O), cesium-carnallite (CsMgCl3·6H2O), bromo-carnallite (KMgBr3·6H2O) and cesium-bromo-carnallite (CsMgBr3·6H2O) were formed by grinding mixtures of MgCl2·6H2O with KCl or CsCl and MgBr2·6H2O with KBr or CsBr, respectively. Hydrated solid solutions of magnesium in potassium or cesium halides were obtained from that portion of potassium and cesium halides which did not take part in the formation of the double salt.",

author = "S. Shoval and S. Yariv",

year = "1998",

doi = "10.1007/BF02719027",

language = "אנגלית",

volume = "51",

pages = "251--263",

journal = "Journal of Thermal Analysis and Calorimetry",

issn = "1388-6150",

publisher = "Springer Netherlands",

number = "1",

}

TY - JOUR

T1 - Formation of carnallite type double salts by grinding mixtures of magnesium and alkali halides with the same anions

AU - Shoval, S.

AU - Yariv, S.

PY - 1998

Y1 - 1998

N2 - The formation of carnallite type double salts by grinding mixtures of hydrated magnesium halide and alkali halides with the same anions was investigated by X-ray diffraction, infrared spectroscopy and thermal analysis. Carnallite (KMgCl3·6H2O), cesium-carnallite (CsMgCl3·6H2O), bromo-carnallite (KMgBr3·6H2O) and cesium-bromo-carnallite (CsMgBr3·6H2O) were formed by grinding mixtures of MgCl2·6H2O with KCl or CsCl and MgBr2·6H2O with KBr or CsBr, respectively. Hydrated solid solutions of magnesium in potassium or cesium halides were obtained from that portion of potassium and cesium halides which did not take part in the formation of the double salt.

AB - The formation of carnallite type double salts by grinding mixtures of hydrated magnesium halide and alkali halides with the same anions was investigated by X-ray diffraction, infrared spectroscopy and thermal analysis. Carnallite (KMgCl3·6H2O), cesium-carnallite (CsMgCl3·6H2O), bromo-carnallite (KMgBr3·6H2O) and cesium-bromo-carnallite (CsMgBr3·6H2O) were formed by grinding mixtures of MgCl2·6H2O with KCl or CsCl and MgBr2·6H2O with KBr or CsBr, respectively. Hydrated solid solutions of magnesium in potassium or cesium halides were obtained from that portion of potassium and cesium halides which did not take part in the formation of the double salt.

UR - http://www.scopus.com/inward/record.url?scp=0032291616&partnerID=8YFLogxK

U2 - 10.1007/BF02719027

DO - 10.1007/BF02719027

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:0032291616

SN - 1388-6150

VL - 51

SP - 251

EP - 263

JO - Journal of Thermal Analysis and Calorimetry

JF - Journal of Thermal Analysis and Calorimetry

IS - 1

ER -

Formation of carnallite type double salts by grinding mixtures of magnesium and alkali halides with the same anions

Abstract

Access to Document

Other files and links

Fingerprint

Cite this