Chemistry and structure of the CH3O2+ product of the O2+ + CH4 reaction

J. M. Van Doren; S. E. Barlow; C. H. DePuy; V. M. Bierbaum; I. Dotan; E. E. Ferguson

doi:10.1021/j100403a043

Chemistry and structure of the CH₃O₂⁺ product of the O₂⁺ + CH₄ reaction

J. M. Van Doren, S. E. Barlow, C. H. DePuy, V. M. Bierbaum, I. Dotan, E. E. Ferguson

Research output: Contribution to journal › Article › peer-review

Abstract

The CH₃O₂⁺ product ion of the thermal energy reaction between O₂⁺ and CH₄ has been studied in reaction with a number of neutral molecules. The reactivity pattern demonstrates very convincingly that the structure of the ion is methylene hydroperoxy cation, CH₂OOH⁺, in contrast to previous reports that the ion is protonated formic acid, HC(OH)₂⁺ or HC(O)OH₂⁺. From these and other data the heat of formation of this ion is determined to be between 182 and 188 kcal/mol.

Original language	English
Pages (from-to)	2772-2777
Number of pages	6
Journal	Journal of Physical Chemistry
Volume	90
Issue number	12
DOIs	https://doi.org/10.1021/j100403a043
State	Published - 1986
Externally published	Yes

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title = "Chemistry and structure of the CH3O2+ product of the O2+ + CH4 reaction",

abstract = "The CH3O2+ product ion of the thermal energy reaction between O2+ and CH4 has been studied in reaction with a number of neutral molecules. The reactivity pattern demonstrates very convincingly that the structure of the ion is methylene hydroperoxy cation, CH2OOH+, in contrast to previous reports that the ion is protonated formic acid, HC(OH)2+ or HC(O)OH2+. From these and other data the heat of formation of this ion is determined to be between 182 and 188 kcal/mol.",

author = "{Van Doren}, {J. M.} and Barlow, {S. E.} and DePuy, {C. H.} and Bierbaum, {V. M.} and I. Dotan and Ferguson, {E. E.}",

year = "1986",

doi = "10.1021/j100403a043",

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journal = "Journal of Physical Chemistry",

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T1 - Chemistry and structure of the CH3O2+ product of the O2+ + CH4 reaction

AU - Van Doren, J. M.

AU - Barlow, S. E.

AU - DePuy, C. H.

AU - Bierbaum, V. M.

AU - Dotan, I.

AU - Ferguson, E. E.

PY - 1986

Y1 - 1986

N2 - The CH3O2+ product ion of the thermal energy reaction between O2+ and CH4 has been studied in reaction with a number of neutral molecules. The reactivity pattern demonstrates very convincingly that the structure of the ion is methylene hydroperoxy cation, CH2OOH+, in contrast to previous reports that the ion is protonated formic acid, HC(OH)2+ or HC(O)OH2+. From these and other data the heat of formation of this ion is determined to be between 182 and 188 kcal/mol.

AB - The CH3O2+ product ion of the thermal energy reaction between O2+ and CH4 has been studied in reaction with a number of neutral molecules. The reactivity pattern demonstrates very convincingly that the structure of the ion is methylene hydroperoxy cation, CH2OOH+, in contrast to previous reports that the ion is protonated formic acid, HC(OH)2+ or HC(O)OH2+. From these and other data the heat of formation of this ion is determined to be between 182 and 188 kcal/mol.

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DO - 10.1021/j100403a043

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JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 12

ER -

Chemistry and structure of the CH₃O₂⁺ product of the O₂⁺ + CH₄ reaction

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