Vibrational relaxation of NO+(υ) by O2(1Δg) molecules

I. Dotan; S. E. Barlow; E. E. Ferguson

doi:10.1016/0009-2614(85)87150-5

Vibrational relaxation of NO⁺(υ) by O₂(¹Δ_g) molecules

I. Dotan, S. E. Barlow, E. E. Ferguson

نتاج البحث: نشر في مجلة › مقالة › مراجعة النظراء

ملخص

The rate constant for NO⁺(υ) vibrational relaxation by metastable O₂(¹Δ_g) molecules is found to be (3±2)×10^-10 cm³ s^-1 at room temperature, in contrast to the lack of vibrational quenching of NO⁺(υ) by ground-state O₂(³Σ) molecules, for which the quenching rate constant <10^-12 cm³ s^-1. This suggests that NO⁺(¹Σ)+O₂(¹Δ) follows a much more attractive potential curve than NO⁺(¹Σ)+O₂(³Σ).

اللغة الأصلية	الإنجليزيّة
الصفحات (من إلى)	38-40
عدد الصفحات	3
دورية	Chemical Physics Letters
مستوى الصوت	121
رقم الإصدار	1-2
المعرِّفات الرقمية للأشياء	https://doi.org/10.1016/0009-2614(85)87150-5
حالة النشر	نُشِر - 1 نوفمبر 1985
منشور خارجيًا	نعم

الوصول إلى المستند

10.1016/0009-2614(85)87150-5

الملفات والروابط الأخرى

Link to publication in Scopus

قم بذكر هذا

@article{2b35e094fdd7432da685990d7350099d,

title = "Vibrational relaxation of NO+(υ) by O2(1Δg) molecules",

abstract = "The rate constant for NO+(υ) vibrational relaxation by metastable O2(1Δg) molecules is found to be (3±2)×10-10 cm3 s-1 at room temperature, in contrast to the lack of vibrational quenching of NO+(υ) by ground-state O2(3Σ) molecules, for which the quenching rate constant <10-12 cm3 s-1. This suggests that NO+(1Σ)+O2(1Δ) follows a much more attractive potential curve than NO+(1Σ)+O2(3Σ).",

author = "I. Dotan and Barlow, {S. E.} and Ferguson, {E. E.}",

year = "1985",

month = nov,

day = "1",

doi = "10.1016/0009-2614(85)87150-5",

language = "אנגלית",

volume = "121",

pages = "38--40",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier",

number = "1-2",

}

TY - JOUR

T1 - Vibrational relaxation of NO+(υ) by O2(1Δg) molecules

AU - Dotan, I.

AU - Barlow, S. E.

AU - Ferguson, E. E.

PY - 1985/11/1

Y1 - 1985/11/1

N2 - The rate constant for NO+(υ) vibrational relaxation by metastable O2(1Δg) molecules is found to be (3±2)×10-10 cm3 s-1 at room temperature, in contrast to the lack of vibrational quenching of NO+(υ) by ground-state O2(3Σ) molecules, for which the quenching rate constant <10-12 cm3 s-1. This suggests that NO+(1Σ)+O2(1Δ) follows a much more attractive potential curve than NO+(1Σ)+O2(3Σ).

AB - The rate constant for NO+(υ) vibrational relaxation by metastable O2(1Δg) molecules is found to be (3±2)×10-10 cm3 s-1 at room temperature, in contrast to the lack of vibrational quenching of NO+(υ) by ground-state O2(3Σ) molecules, for which the quenching rate constant <10-12 cm3 s-1. This suggests that NO+(1Σ)+O2(1Δ) follows a much more attractive potential curve than NO+(1Σ)+O2(3Σ).

UR - http://www.scopus.com/inward/record.url?scp=4243269088&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(85)87150-5

DO - 10.1016/0009-2614(85)87150-5

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:4243269088

SN - 0009-2614

VL - 121

SP - 38

EP - 40

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-2