Stereospecific Radical Bromination of ß‐Aryl Alcohols with Thiourea Additives Through A Serendipitous Discovery of A 1,2‐Aryl Migration

Keyphrases

• Thiourea 100%
• Radical Bromination 100%
• Stereospecific 100%
• Serendipitous Discovery 100%
• Aryl Alcohols 100%
• Bromination 66%
• Phenyl 66%
• Halo 33%
• Wide Scope 33%
• Substoichiometric 33%
• Halogenation 33%
• Alcohol 33%
• Mild Reaction Conditions 33%
• Pharmaceutical Industry 33%
• 1,2-migration 33%
• Apolar Solvents 33%
• Halogens 33%
• Phenyl Migration 33%
• Chemical Industry 33%
• Bromination Reaction 33%
• 2-Butanol 33%
• Stereochemical Hypothesis 33%
• Racemate 33%
• Chiral Secondary Alcohols 33%
• Spiro 33%
• Stereoisomeric 33%
• Succinimide 33%
• Alkyl Chlorides 33%
• Phenyl Group 33%
• Cyclopropanols 33%
• Bromide Radical 33%
• Alkyl Bromide 33%
• Retention of Configuration 33%
• Stereoselectivity 33%
• Brominated Products 33%

Chemistry

• Thiourea 100%
• bromination 100%
• Secondary Alcohol 25%
• formation 25%
• halogenation 25%
• Halogen 25%
• Butene 25%
• Pharmaceutical Industry 25%
• Phenyl Group 25%
• Racemate 25%
• Chemical Industry 25%
• Diastereomer 25%