TY - JOUR
T1 - Energy dependences of the reactions of Ar+ with H2, N2, CO, O2, CO2, N2O, and COS
AU - Dotan, I.
AU - Lindinger, W.
N1 - Copyright:
Copyright 2020 Elsevier B.V., All rights reserved.
PY - 1981
Y1 - 1981
N2 - Reactions of Ar+ ions with H2, N2, O 2, CO CO2, N2O, and COS have been meausred in a flow-drift tube at center-of-mass energies of 0.04-2.5 eV. The reactions with H2 and COS are fast and show only small energy dependences. The reaction with N2 is very slow at thermal energies and the rate coefficient increases very fast with increasing energy. The rate coefficients for the reactions with CO2 and N2O decrease with increasing energy over the whole energy range studied. For the reactions with O2 and CO, we find minima of the rate coefficient at 0.4 and 0.8 eV, respectively, followed by a dramatic increase at higher energies.
AB - Reactions of Ar+ ions with H2, N2, O 2, CO CO2, N2O, and COS have been meausred in a flow-drift tube at center-of-mass energies of 0.04-2.5 eV. The reactions with H2 and COS are fast and show only small energy dependences. The reaction with N2 is very slow at thermal energies and the rate coefficient increases very fast with increasing energy. The rate coefficients for the reactions with CO2 and N2O decrease with increasing energy over the whole energy range studied. For the reactions with O2 and CO, we find minima of the rate coefficient at 0.4 and 0.8 eV, respectively, followed by a dramatic increase at higher energies.
UR - http://www.scopus.com/inward/record.url?scp=36749118714&partnerID=8YFLogxK
U2 - 10.1063/1.442843
DO - 10.1063/1.442843
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AN - SCOPUS:36749118714
SN - 0021-9606
VL - 76
SP - 4972
EP - 4977
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
IS - 10
ER -