Energy dependence of the O- transfer reactions of O 3- and CO3- with NO and SO 2

D. L. Albritton, I. Dotan, G. E. Streit, D. W. Fahey, F. C. Fehsenfeld, E. E. Ferguson

نتاج البحث: نشر في مجلةمقالةمراجعة النظراء

ملخص

The O transfer reactions of O3- and CO 3- with NO and SO2 were measured as a function of temperature in the range 170-605 K in a variable-temperature flowing afterglow system and as a function of center-of-mass kinetic energy in the range 0.04-2 eV in a flow-drift tube system. The rate constant in each case showed a marked energy dependence. The rate constants measured as a function of temperature were essentially the same as those measured as a function of kinetic energy in He and Ar buffer gases when the comparison is made at the same mean center-of-mass kinetic energy. The results imply that the reactions have negligible vibrational or rotational energy dependence.

اللغة الأصليةالإنجليزيّة
الصفحات (من إلى)6614-6619
عدد الصفحات6
دوريةJournal of Chemical Physics
مستوى الصوت78
رقم الإصدار11
المعرِّفات الرقمية للأشياء
حالة النشرنُشِر - 1983
منشور خارجيًانعم

بصمة

أدرس بدقة موضوعات البحث “Energy dependence of the O- transfer reactions of O 3- and CO3- with NO and SO 2'. فهما يشكلان معًا بصمة فريدة.

قم بذكر هذا