ملخص
The O transfer reactions of O3- and CO 3- with NO and SO2 were measured as a function of temperature in the range 170-605 K in a variable-temperature flowing afterglow system and as a function of center-of-mass kinetic energy in the range 0.04-2 eV in a flow-drift tube system. The rate constant in each case showed a marked energy dependence. The rate constants measured as a function of temperature were essentially the same as those measured as a function of kinetic energy in He and Ar buffer gases when the comparison is made at the same mean center-of-mass kinetic energy. The results imply that the reactions have negligible vibrational or rotational energy dependence.
اللغة الأصلية | الإنجليزيّة |
---|---|
الصفحات (من إلى) | 6614-6619 |
عدد الصفحات | 6 |
دورية | Journal of Chemical Physics |
مستوى الصوت | 78 |
رقم الإصدار | 11 |
المعرِّفات الرقمية للأشياء | |
حالة النشر | نُشِر - 1983 |
منشور خارجيًا | نعم |